基于源质的煤基中间相小球体生成与可控演化

煤全组分族分离所得的密中质组是中间相小球体生成的来源物质（即源质）。以该源质为原料，制备煤基碳质中间相。考察了炭化过程中温度、恒温时间、氮气流速、原料进样方式和添加剂等因素对中间相小球体生成过程的影响，探讨了中间相小球体演化过程的可控性。结果表明：温度、恒温时间、进样方式是影响中间相小球体生成的主要因素，能够控制生成中间相小球体粒径大小；温度升高或恒温时间延长均会加剧原料分子的热反应，促进中间相小球体的生成和融并；大面积的融并将使粒度迅速增加，部分球体解体，球体数目下降，最终形成体中间相；进样方式主要通过影响小球体演化过程中挥发性气体的逸出及原料颗粒间热传递效率影响小球体的生成和发展；氮气流速起到辅助调控作用；添加剂的加入促进了原料成核，加速了小球体的生成。     

Retrofitting of the Heat Exchanger Network with Steam Generation in a Crude Oil Distillation Unit

Steam generation through hot streams has an important impact on the utility consumption of a crude oil distillation unit. Retrofitting of the heat exchanger network with steam generation in a crude oil distillation unit is studied with regard to efficient energy usage. The grand composite curve is employed to provide insights into the steam generation problem, and a mixed‐integer linear programming model, presented previously for heat integration through hot discharges/feeds and steam generation, is used to obtain the optimal parameters for steam generation. Three heuristic rules are then proposed to determine suitable hot streams for steam generation. Finally, the heat exchanger network is modified based on pinch technology. After the retrofit, the hot and cold utility decrease.     

Assessing Cloud Transient Impacts of Solar and Battery Energy Systems on Grid Inertial Responses

To assess the dynamic impact of intermittency of rapidly increasing solar photovoltaic generation on the grid, this article presents the modeling and integration of the components that need to be considered, including the solar photovoltaic plant, battery energy storage system, grid-tied interface, and associated control systems. The complexity and accuracy of these models are suitable for evaluating the transient impact on bulk power systems. Of particular interest is the grid inertial response in such situations as different penetration levels of solar generation and fast cloud transient induced solar generation decrease coupled with outages that recurrently occur in the grid, e.g., a generator trip. The impact of such events on the grid frequency responses is investigated using a simplified simulation approach to account for the locational or spatial irradiance variation patterns and cloud movements. Responsive battery energy storage systems are recognized as an effective means to improve the inertial response.     

换能器结构参数对聚合物超声塑化黏弹生热的影响

为研究超声换能器结构参数对聚合物超声塑化过程黏弹性生热的影响，首先确定超声黏弹性生热系统的组成，进行纵振超声换能器结构设计；然后分析超声黏弹性生热过程及超声黏弹性生热原理；最后采用单一变量法分析超声换能器的主要结构参数对其纵振频率及工具头前端质点最大振幅的影响，将其实际输出的纵振激励加载于熔融聚合物，研究其结构参数对聚合物超声黏弹性生热过程及达到聚合物玻璃化转变温度所用时间的影响。结果表明，随纵振激励作用时间的增加，聚合物温度非线性升高；放大比对聚合物温度变化影响最大，前盖板厚度和工具头长度次之，影响最小的是变幅杆长度。     

热电厂供电运行故障及应对措施探讨

长期高负荷、高输出的热电厂供电运作过程中不可避免地出现设备磨损等故障。为了做好供电运行中的故障预防以及有效维护,开展了热电厂供电运行故障及应对措施探讨。分析了造成设备磨损、备用电源失效、发电设备电压不稳定、电力接地短路、发电设备温度过高等故障原因,并提出了有针对性的解决方法,以保障热电厂供电系统的正常运转。分析认为,遇到不同的电力故障问题,应具体分析、区别对待,并在检修的过程中及时总结经验;对于设备本身的问题,应最大程度以技术创新弥补自身结构缺陷。     

Hydrogen production by electrochemical methanol reformation using alkaline anion exchange membrane based cell

Electrochemical methanol reformation (ECMR) is an alternative promising technology for producing hydrogen at low energy consumption compared to water electrolysis. In this process, solid polymer electrolyte Nafion® is widely employed, due to its superior proton conductivity. However, major limitations are the utilisation of expensive platinum based catalysts, high cost of the above membrane and the crossover of methanol through the polymer electrolyte membrane. In the present work, attempt has been to made to use low cost polymer electrolyte membrane and less noble electro catalyst. A series of Anion Exchange Membranes (AEM) are synthesized from Poly (2, 6-dimethyl-1, 4-phenylene oxide) (PPO) for its application in ECMR. PPO is successfully made into anion conducting by chloromethylation followed by quaternization. Two AEM's are synthesized by optimizing chloromethylation reaction time to 5 h and quaternization time to 5 and 8 h and are labelled as QPPO (C5, Q5) and QPPO (C5, Q8) respectively. Further, with the view to improve the anion conductivity further, composite AEMs are prepared by incorporating inorganic anion conducting quaternized graphene oxide particles in the matrix of PPO and QPPO (C5, Q8) polymers separately to obtain two polymers PPO/QGO and QPPO/QGO. The anionic conductivity of PPO/QGO and QPPO/QGO polymer is 1.2 × 10⁻⁴ and 1.5 × 10⁻⁴ S cm⁻¹ respectively. Both the membranes are subjected as electrolyte for ECMR application using membrane electrode assembly made by with in house synthesized nitrogen doped graphene supported Pd catalyst (Pd/NG) as anode catalyst and commercial Pt/C as cathode catalyst. The performance of composite membrane was compared with the commercial Fumasep® FAA anion exchange membrane. The polarization studies of ECMR cell with composite membrane shows comparable performance with that of commercial Fumasep® FAA-2 FAA membrane. The durability of the membrane(s) in the electrolysis environment was tested for about 20 h.     

Optimal control strategy of a DC micro grid

Microgrids include distributed energy resources, controllable loads, and storage devices, and they can be classified into AC and DC types, depending on the characteristics of the supply voltage. In this paper, an optimal control strategy for a DC microgrid is proposed, and the strategy is aimed at minimizing the daily total energy costs. The DC micro grid can include non-dispatchable generation units (such as photovoltaic power generation) and dispatchable generation units, energy storage systems (batteries), and controllable/not controllable loads. The control strategy is based on a two-step procedure, i.e., (1) the implementation of one day-ahead scheduling and (2) a very short-time predictive control. The day-ahead scheduling is formulated using integer linear programming methodology and is aimed at achieving the optimal scheduling of controllable loads. The very short-time predictive control is based on the solution of a non-linear, multi-period, optimization problem and is aimed at achieving the real-time optimal charging/discharging profile of storage powers and the real-time optimal profile of powers of dispatchable generators thereby minimizing the cost of total daily energy. For both procedures, optimization models were formulated and solved, including technical constraints that guaranteed an adequate lifetime of the storage system. Case studies relative to a DC microgrid obtained by a modification of the actual structure of the electrical power plant of an Italian industrial facility were investigated in order to show the feasibility and the effectiveness of the proposed approach.     

The minimization of voltage sag effect for specially connected transformers with a sensitive load and distributed generation systems

This paper improves the voltage sag for a distributed generation (DG) system with three-phase to two-phase connected transformers. The proposed connection system is compared with the systems designed by Scott and Le Blanc. A particle swarm optimization method with nonlinear time-varying evolution (PSO-NTVE) is used to determine the design values. This analysis considers sensitive loads and the coordination of over-current relays. The model uses a node admittance matrix for voltage sag calculation, in order to calculate the severity of system sag after single or two-phase faults. The analytical equations are useful in the mathematical optimal planning method. The PSO-NTVE is then used to derive suitable transformer impedances and relay time multiplier parameter values. The search for a global optimal solution for the voltage sag problems involves tests on the Scott and Le Blanc connected transformer power systems, in order to verify the effectiveness of the proposed method. Finally, the results show that the severity of the voltage sag is reduced by tuning the transformer impedances and relay settings.     

Fully distributed tracking control for non‐identical multi‐agent systems with matching uncertainty

This article addresses the fully distributed consensus tracking control problem of linear multi‐agent systems with parameter uncertainties. First, a new class of distributed protocol, based on the relative states of neighbors, is proposed. Theoretical analysis indicates that the considered problem can be solved if the control gain constant of the protocol is larger than the norm bound of the leader's nonlinear inputs. Furthermore, a distributed adaptive control protocol is proposed for the case without available global information. The distributed consensus tracking control problem of uncertain linear multi‐agent systems is solved based only on local information under the proposed adaptive protocol. Finally, an application in low‐Earth‐orbit satellite formation flying is provided to illustrate the theoretical results. Copyright © 2014 John Wiley & Sons, Ltd.     

A Hydrogen Management Method in Residential Distributed Generation Systems with Photovoltaic Cells and Hydrogen‐Storage Type Fuel Cells

Recently, renewable energy has been attracting attention as a result of global warming and the depletion of fossil fuels. Photovoltaic (PV) systems have spread rapidly around the world because they generate electric power quietly and can be installed in many places. The output power generated in a PV system fluctuates with changes in solar irradiance and panel temperature. The reverse flow of surplus power in output spikes may have a negative effect on electric power quality, such as on the frequency and voltage in a power system. A residential distributed generation (DG) system composed of a fuel cell (FC) unit, an electrolyzer (EL) unit, and a PV system has been proposed in order to resolve these problems. In order to operate this system without interruption, the hydrogen storage volume must be managed. This paper proposes a novel hydrogen management method for a residential DG system with PV cells and hydrogen‐storage type FCs. The hydrogen storage volume is maintained at the preset frequency by operating the FC unit and the EL unit. Models of the PV, FC, and EL were constructed for a simulation. In the simulation, we showed that the proposed management method is viable for a residential DG system with PV cells and hydrogen‐storage FCs.